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ABSTRACT

Stability Constants of Mixed Ligand Complexes of Transition Metal(II) ions with2-{(E)-[(4-bromo-2-methylphenyl)imino]methyl}phenoland1-[(E)-(4-bromonaphthalen-1-ylimino)methyl]naphthalen-2-ol.

Santosh B Katariya

ABSTRACT

Binary and ternary complexes of the type M-Y and M-X-Y [M = Cu(II) , Ni(II) ,Co(II) , Zn(II); X = 2-{(E)-[(4-bromo-2-methylphenyl)imino]methyl}phenol and Y =1-[(E)-( 4-bromonaphthalen-1-ylimino)methyl]naphthalen-2-ol]have been examined pH-metrically at27 ± 0.5oC and at constant ionic strength, ? = 0.1M (KCl) in 75 : 25 (v/v) 1,4-dioxne-water medium. The stability constants for Binary (M-Y) and ternary (M-X-Y) systems were calculated. Keywords:Binary complexes, Ternary complexes, Mixed ligand, Stability constant.

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