Review Article
Open Access
Advances in the coordination chemistry of transition metal compounds applying nitrogen and sulphur containing ligand : Synthesis, Structural and properties consideration.
Mohammad Tarique
Department of Chemistry, BITS, Ghaziabad, India.
Mohammad Tarique/Int.J Chemical Concepts 2015,1(1), pp 34-37.
Abstract
This paper deals with the synthesis of sulphur and nitrogen containing dithiocarbamate ligand
derived from 2-naphthylylamine as well as its coordination compounds with d-block metals of first series.
Characterization of these compounds was made through elemental analysis, conductometric measurements
and IR spectral studies. The analytical data showed the stoichiometry 1:2 and 1:3 for the compounds of the
types ML2 {M=Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)} and M’L3 {M’=Cr(III) and Fe(III)}, respectively.
The conductometric measurements indicated the compounds to be non-ionic in nature. The bidentate nature
of dithiocarbamato moiety was confirmed on the basis of FT-IR spectral data.
Keywords
Transition metal chelates, Dithiocarbamates, IR and conductance.
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